Philadelphia and Phoenix are about 2,078 miles apart by road. Split the difference and you arrive near Kansas City, the city closest to the halfway point between them. That splits the trip almost evenly — about 21 hr 41 min from Philadelphia and 21 hr 58 min from Phoenix.
Over this distance most people will fly rather than drive the whole way. Kansas City still makes a fair, central place for Philadelphia and Phoenix to converge, splitting the travel instead of asking one side to cross the country.
If Kansas City doesn't have what you're after, Memphis and Oklahoma City are also close to the midpoint and worth a look — each keeps the drive reasonably balanced between Philadelphia and Phoenix.
City descriptions adapted from Wikipedia (CC BY-SA); photos via Wikimedia Commons, credited above.