Phoenix and Washington are about 1,978 miles apart by road. Split the difference and you arrive near Oklahoma City, the city closest to the halfway point between them. That puts roughly 17 hr 37 min of driving on the Phoenix side and 24 hr 6 min on the Washington side — the fairest single meeting point among the cities near the middle.
Over this distance most people will fly rather than drive the whole way. Oklahoma City still makes a fair, central place for Phoenix and Washington to converge, splitting the travel instead of asking one side to cross the country.
If Oklahoma City doesn't have what you're after, Kansas City and Memphis are also close to the midpoint and worth a look — each keeps the drive reasonably balanced between Phoenix and Washington.
City descriptions adapted from Wikipedia (CC BY-SA); photos via Wikimedia Commons, credited above.